Serveur d'exploration sur le cobalt au Maghreb

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AgCo3PO4(HPO4)2

Identifieur interne : 000B17 ( Main/Exploration ); précédent : 000B16; suivant : 000B18

AgCo3PO4(HPO4)2

Auteurs : Abderrahmen Guesmi [Tunisie] ; Ahmed Driss [Tunisie]

Source :

RBID : ISTEX:03BDBE7015658DF802D344DF6A3E7BA5DC8CCC4E

Abstract

The structure of the hydro­thermally synthesized compound AgCo3PO4(HPO4)2, silver tricobalt phosphate bis­(hydrogen phosphate), consists of edge‐sharing CoO6 chains linked together by the phosphate groups and hydrogen bonds. The three‐dimensional framework delimits two types of tunnels which accommodate Ag+ cations and OH groups. The title compound is isostructural with the compounds AM3H2(XO4)3 (A = Na or Ag, M = Co or Mn, and X = P or As) of the alluaudite structure type.

Url:
DOI: 10.1107/S0108270101017759


Affiliations:


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